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Beilstein J. Org. Chem. 2015, 11, 1933–1943, doi:10.3762/bjoc.11.209
Graphical Abstract
Scheme 1: Generation of iminyl radicals from oxime derivatives.
Scheme 2: Oxidative generation of iminyl radicals from N–H ketimines.
Scheme 3: Copper-catalyzed aerobic reactions of in situ generated biaryl N–H ketimines.
Scheme 4: Copper-catalyzed aerobic C–C bond cleavage reactions of N–H ketimines.
Scheme 5: Proposed reaction mechanisms for the formation of 3a, 4a and 5a, and the reaction of hydroperoxide 6...
Scheme 6: Formation of bromoketone 6e.
Scheme 7: Electrophilic cyanation of Grignard reagents with pivalonitrile (1f).
Scheme 8: Electrophilic cyanation with pivalonitrile (1e).